Ron: You are correct that a US N-registered plane operating under Part 91 is only required to be serviced under the Chapter 4 "Airworthiness Limitations" of the AMM. Chapter 5 maintenance items are all optional at the discretion of the owner.
As for my first 100 hour (not an annual inspection) service on a DA62, I only performed the oil and filter changes. To save money (and because I enjoy tinkering with my plane), I did it all by myself, since replacement of these items is legal for the owner to perform without supervision by a licensed A&P.
Diamond sells "100 hour kits" for Austro engines that provide you with a genuine Mercedes oil filter for Mercedes OM640 auto diesel engines (upon which your AE330s are based), a MANN WK 724/3 fuel filter, a paper "coffee filter" for straining your gearbox oil to look for metal (oil that you pour right back into the gearbox, replacing it only every 300 hours), some copper crush washers, and an oil sample container for mailing your oil to Austria for analysis. IMHO these 100 hour kits are a ripoff, especially since I learned (with my DA42-VI's Austro engines) that after you pay all the international shipping to send an oil sample to Austro Engine in Austria, they never bother to get back to you with any results. And of course as a US DA62 owner you're already paying for international shipping of the 100 hour kits from Canada.
So for my first 100 hour service on my DA62 last year, I used:
- Castrol Edge 0W-40 A3/B4 European formula car full synthetic engine oil from my local Walmart (available in 5 quart and 1 quart containers); this is one of the many approved oils listed in the Austro Engine maintenance manual, but one of the few that is readily-available in the US.
- New genuine Mercedes oil filters bought from a supplier on Ebay in the UK. I learned that this filter is actually made by MANN in Germany for Mercedes-Benz; you can purchase the MANN-branded engine oil filters even more cheaply from many European suppliers who will ship to the US. The MANN part is: HU615/3x
- New MANN WK 324/3 fuel filters identical to the ones included in the Diamond kits, also obtainable from European suppliers who ship to the US.
- Blackstone Labs oil analysis kits. These US guys can analyze diesel engine oil and provide great feedback on your Austro engine oil samples.
http://www.blackstone-labs.com
You will also need to learn how to safety wire a few bolts/plugs on the engine (purchase a safety wire tool kit from a place like Aircraft Spruce) -- safety wiring is not very difficult. And you'll need to purchase a long 8mm threaded bolt (M8x50 or longer) from your favorite local hardware store that's used to easily extract the small oil filter from each engine gearbox (you'll examine that filter for potential metal contamination and then put it back in).
Since you're flying a plane with automotive engines, it's nice to be able to utilize standard automotive oils and filters, all of which can be found with some Internet searching.
Let me suggest that you and your mechanic might want to purchase Diamond's 100 hour kits for your DA62's first 100 hour servicing, just so you can see what's included in the kits. After that, you might want to consider alternate sources as noted above.